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Abstract. The primary scientific objective of MexiDrill, the Basin of MexicoDrilling Program, is development of a continuous, high-resolution∼400 kyr lacustrine record of tropical North Americanenvironmental change. The field location, in the densely populated,water-stressed Mexico City region gives this record particular societalrelevance. A detailed paleoclimate reconstruction from central Mexico willenhance our understanding of long-term natural climate variability in theNorth American tropics and its relationship with changes at higher latitudes.The site lies at the northern margin of the Intertropical Convergence Zone(ITCZ), where modern precipitation amounts are influenced by sea surfacetemperatures in the Pacific and Atlantic basins. During the Last GlacialMaximum (LGM), more winter precipitation at the site is hypothesized to have beena consequence of a southward displacement of the mid-latitude westerlies. Itthus represents a key spatial node for understanding large-scalehydrological variability of tropical and subtropical North America and isat an altitude (2240 m a.s.l.), typical of much of western North America. In addition, its sediments contain a rich record of pre-Holocene volcanichistory; knowledge of the magnitude and frequency relationships of thearea's explosive volcanic eruptions will improve capacity for riskassessment of future activity. Explosive eruption deposits will also be usedto provide the backbone of a robust chronology necessary for fullexploitation of the paleoclimate record. Here we report initial resultsfrom, and outreach activities of, the 2016 coring campaign. 

Abstract High‐resolution mass spectrometry (HRMS) has become a vital tool for dissolved organic matter (DOM) characterization. The upward trend in HRMS analysis of DOM presents challenges in data comparison and interpretation among laboratories operating instruments with differing performance and user operating conditions. It is therefore essential that the community establishes metric ranges and compositional trends for data comparison with reference samples so that data can be robustly compared among research groups. To this end, four identically prepared DOM samples were each measured by 16 laboratories, using 17 commercially purchased instruments, using positive‐ion and negative‐ion mode electrospray ionization (ESI) HRMS analyses. The instruments identified ~1000 common ions in both negative‐ and positive‐ion modes over a wide range ofm/zvalues and chemical space, as determined by van Krevelen diagrams. Calculated metrics of abundance‐weighted average indices (H/C, O/C, aromaticity, andm/z) of the commonly detected ions showed that hydrogen saturation and aromaticity were consistent for each reference sample across the instruments, while average mass and oxygenation were more affected by differences in instrument type and settings. In this paper we present 32 metric values for future benchmarking. The metric values were obtained for the four different parameters from four samples in two ionization modes and can be used in future work to evaluate the performance of HRMS instruments.